Modelling Chemical Clocks – Theoretical Evidences of the Space and Time Evolution of [s/alpha] in the Galactic Disc with Gaia-ESO Survey

Chemical clocks based on [s-process elements/alpha-elements] ratios are widely used to estimate ages of Galactic stellar populations. However, the [s/alpha] vs. age relations are not universal, varying with metallicity, location in the Galactic disc, and specific s-process elements. Current Galactic chemical evolution models struggle to reproduce the observed [s/alpha] increase at young ages. We provide chemical evolution models for the Milky Way disc to identify the conditions required to reproduce the observed [s/H], [s/Fe], and [s/alpha] vs. age relations. We adopt a multi-zone chemical evolution model including state-of-the-art nucleosynthesis prescriptions for neutron-capture elements (AGB stars, rotating massive stars, neutron star mergers, magneto-driven supernovae). We explore variations in gas infall, AGB yield dependencies on progenitor stars, and rotational velocity distributions for massive stars. Results are compared with open cluster data from the Gaia-ESO survey. A three-infall scenario for disc formation captures the rise of [s/alpha] with age in the outer regions but fails in the inner ones, especially for second s-process peak elements. Ba production in the last 3 Gyr of chemical evolution would need to increase by half to match observations. S-process contributions from low-mass AGB stars improve predictions but require increases not supported by nucleosynthesis calculations, even with potential i-process contribution. Variations in the metallicity dependence of AGB yields show inconsistent effects across elements. Distributions of massive star rotational velocities fail to improve results due to balanced effects on elements. We confirm that there is no single relationship [s/alpha] vs. age, but that it varies along the MW disc. Current prescriptions for neutron-capture element yields cannot fully capture the complexity of evolution, particularly in the inner disc.