Deciphering Fungal Metabolon Coupling Tandem Inverse-Electron-demand Diels-Alder Reaction and Semipinacol Rearrangement for the Biosynthesis of Spiro Polycyclic Alkaloids

Shuai Liu, Wen-Qiang Xu,Ying-Tong Di,Man-Cheng Tang, Ding-Kang Chen,Ming-Ming Cao, Yao-Wen Chang, Hong-Yu Tang, Chun-Mao Yuan,Jun-Bo Yang,Zhi-Li Zuo, Han Guo, Zi-Fei Xu,Ying Zeng,Yun-Dong Wu,Xiao-Jiang Hao

Science China Chemistry（2024）

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关键词

metabolon,Diels-Alder reaction,semipinacol rearrangement,biosynthesis,notoamides,spiro polycyclic alkaloids

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