Comparative Study of Titanium Complexes Bearing 2-(Arylideneamino)phenolates and 2-((Arylimino)methyl)phenolates As Catalysts for Ring-Opening Polymerization of Ε‑caprolactone and L-Lactide

Ling-Jo Wu,Ravi Kumar Kottalanka,Yu-Ting Chu,Zheng-Ian Lin,Chun-Juei Chang,Shangwu Ding,Hsuan-Ying Chen, Kuo-Hui Wu,Chih-Kuang Chen

Dalton transactions (Cambridge, England 2003)（2024）

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摘要

Titanium complexes bearing 2-(arylideneamino)phenolates and 2-((arylimino)methyl)phenolates were synthesized, and their catalytic activities in the polymerization of ε-caprolactone and L-lactide were studied. Among five-membered ring Ti complexes bearing 2-(arylideneamino)phenolates, FCl-Ti exhibited...

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