Synergizing ruthenium oxide with bimetallic Co2CrO4 for highly efficient oxygen evolution reaction

Designing efficient and stable oxygen evolution reaction (OER) catalyst is the basis for the development of sustainable electrolytic water energy techniques. In this work, we presented a heterogeneous-structured electrocatalyst composed of bimetallic oxides-modified RuO2 nanosheets supported on nikel foam (Co2CrO4/RuO2) using a hybrid hydrothermal, ion-exchange and calcination method. The unique synergy and interfacial coupling between Co2CrO4/RuO2 heterostructures are favorable for optimizing the electronic configuration at this interface and strengthening the charge transport capacity, thus strengthening the catalytic activity of the Co2CrO4/RuO2 catalyst. The experimental data demonstrate that Cr leaching facilitates the rapid reconstruction of the catalyst into oxyhydroxides (CoOOH), which are acknowledged to be the real active species of OER. Theoretical calculations show that the Co2CrO4/RuO2 heterostructure increases the density state at the Fermi energy level and lowers the d-band center, thereby strengthening the catalytic activity. The synthesized Co2CrO4/RuO2 catalyst exhibited OER performance with an overpotential of 209 mV at 10 mA cm−2 and displayed a low Tafel slope of 78.2 mV dec-1, which outperforms most reported advanced alkaline OER catalysts. This work contributes to a new tactic for the design and development of ruthenium oxide/bimetallic oxides electrocatalysts.