Carbon Nitride Coupled Two-Dimensional Metal–organic Framework Core–shell Catalyst for Photo-Enzymatic Synergistic Degradation of Bisphenol A

Bisphenol A (BPA), as a typical endocrine disruptor, can cause serious harm to human health. In order to solve the limitation of biological enzyme method in the degradation of BPA in actual water, we successfully prepared a photo-enzyme-coupled catalyst CN-HRP@ZIP by in situ generation of a metal–organic skeleton coated with HRP on the carbon nitride surface. The photo-enzymatic synergy of the material and the low mass transfer resistance caused by the two-dimensional ZIP make CN-HRP@ZIP can achieve 100