Exploring Microfine Magnesite Based on Thermal Decomposition and Sintering Kinetics: A New Direction in the One-step Preparation of High-Density Sintered Magnesia

The thermal decomposition and sintering kinetics of microfine magnesite were investigated to inaugurate a new One-step process for preparing high-density sintered magnesia. The optimal parameters for the discharging particle size of magnesite through ball milling were determined using an orthogonal experiment and Three-Way Measures ANOVA. The model for the thermal decomposition process of microfine magnesite was established through TGA-DSC and nonlinear regression analysis. Meanwhile, by describing the sintering process of microfine magnesite in detail through microstructure and CTE, the kinetic mechanisms of grain growth at different sintering stages were obtained. The results revealed that increasing the ratio of ball to powder can quickly obtain microfine magnesite which the bulk density reaches 3.45 g·cm−3 after One-step sintering. The thermal decomposition process required an activation energy of only 124.98 kJ·mol−1, which is much lower than existing technology and followed the Two-dimensional phase boundary reaction mechanism R2. Additionally, the densification process was dominated alternatively by grain boundary diffusion and volume diffusion. This paper provided a detailed theoretical basis and leads a new direction in the One-step preparation of high-density sintered magnesia.