Nickel(0)-Catalyzed Ring Opening Reaction of Silacyclobutanes with 1,3-Dienes to Access Allylsilane

Mengyuan Liu, Kexin Dong,Bing Xu,Zhan-Ming Zhang,Zhong Wei,Junliang Zhang

ORGANIC CHEMISTRY FRONTIERS（2024）

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摘要

Here we report a Ni-catalyzed highly regio- and stereoselective ring opening reaction of SCBs with 1,3-dienes for straightforward and facile preparation of allylsilanes. This chemistry involves the cleavage and reconstruction...

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