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One-pot Synthesis of TiO2-decorated SnSe/ZnS As a Novel Anode Material with Promoted Storage Capacity and Cyclability in Lithium-Ion Batteries

Journal of Materials Science Materials in Electronics(2024)

Central Metallurgical Research & Development Institute | Imam Mohammad Ibn Saud Islamic University (IMSIU)

Cited 1|Views10
Abstract
New metal oxide-metal chalcogenide system composed of TiO2@SnSe-ZnS composite was synthesized via one-step solvothermal process. XRD, FTIR, and Raman results confirmed the presence of mixed phases and corresponding molecular bonding of rutile TiO2, cubic ZnS, and orthorhombic SnSe. FESEM and TEM characterizations showed a unique interference between two distinguished morphologies, where TiO2 appeared as nanoflakes covering the spherical particles of ZnS/SnSe. XPS inspection of TiO2-modified SnSe-ZnS sample showed that small portion of the existed Zn2+ in tetrahedral sites is displaced into the octahedral sites as a result of the lattice distortion by incorporation of Ti4+/Ti3+ cations and oxygen deficiency in the structure. The initial specific discharge capacity for the modified SnSe-ZnS anode with 3
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要点】:本文提出了一种新型TiO2@SnSe-ZnS复合阳极材料,通过一步溶剂热过程合成,显著提高了锂离子电池的存储容量和循环性能。

方法】:采用一步溶剂热过程合成TiO2@SnSe-ZnS复合物,通过XRD、FTIR、Raman、FESEM和TEM等技术对材料进行了详细表征。

实验】:通过电化学测试,新型阳极材料在初始放电时展现出高比容量,并使用了一个未明确指出的数据集来评估其循环性能,结果显示材料具有良好的循环稳定性和存储容量。