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Fluorescent Carbon Dots Crosslinked Salix Psammophila Microcrystalline Cellulose Interpenetrating Hydrogel System for Sensitive Detection and Efficient Adsorption of Fe3+

MICROCHEMICAL JOURNAL(2024)

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摘要
To combat the contaminating effects of heavy-metal ions on water resources, we prepared blue photonitrogendoped carbon quantum dots (NCDs) from Salix psammophila (SP) as a raw material, doped them into a microcrystalline cellulose hydrogel, and successfully created a composite hydrogel (NCDs-SP-MCC-gels) for concurrent fluorescence detection and Fe3+ adsorption. The NCDs-SP-MCC-gels was examined for their shape, chemical composition, fluorescence characteristics, and adsorption behaviors. Results demonstrated that the NCDs-SPMCC-gels displayed a broad linear range of Fe3+ fluorescence response (200-1000 mg/L; detection limit = 3.90583 mg/L) and a high adsorption capacity for Fe3+ (610 mg/g). The adsorption data fitted the Langmuir and pseudo-second-order models well. Further research was conducted on Fe3+ detection and adsorption onto the NCDs-SP-MCC-gels. This study proposes a green and sustainable way to create a material for the detection and absorption of heavy-metal ions.
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关键词
Cellulose,Carbon quantum dots,Detection,Adsorption
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