Triboelectric nanogenerators based on hydrated lithium ions incorporated double-network hydrogels for biomechanical sensing and energy harvesting at low temperature
NANO ENERGY(2024)
摘要
Conductive hydrogels with flexibility, anti-freezing ability and functionality have garnered significant attention in developing of advanced triboelectric nanogenerators (TENGs). Herein, a tough, adhesive, and anti-freezing ionic double-network conductive hydrogel (referred as Glu/P(HEA-co-AA)-Fe/LiCl) was prepared by choosing glucan as the first network, Fe3+-COO- metal coordination crosslinked poly(2-Hydroxyethyl acrylate-co-acrylic acid) (P(HEA-co-AA) as the second network, which were crosslinked by multiple hydrogen bonds in the presence of hydrated lithium ions ([Li(H2O)(n)](+)). The hydrogel exhibited excellent mechanical properties (toughness of 16.26 MJ/m(3), tensile stress of 4.15 MPa, tensile strain of 1213%, compressive stress of 2.98 MPa under 80% compressive strain), strong adhesion (30.84 kPa for Ecoflex), and satisfactory conductivity (0.43 S/m) even at -18 degrees C. The TENGs based on Glu/P(HEA-co-AA)-Fe/LiCl hydrogel (GP-TENGs) proved its applicability to display excellent electrical output performance (V-OC = 182.42 V, I-SC = 2.61 mu A, and Q(SC) = 63.37 nC) at 25 degrees C, outstanding fatigue resistance (> 5000 consecutive taps), and long-term anti-freezing ability (a V-OC of 163.58 V after one-month cryostorage). Furthermore, GP-TENGs can be utilized as biomechanical sensor with ultra-low pressure detection limit (0.016 kPa) and high pressure sensitivity of 0.336 kPa(-1) (0.016-1.6 kPa), capable of accurately detecting various human motions, also as energy harvesting devices to power small electronic devices with self-powered systems operating at -18 degrees C. This study developed a strategy for building an anti-freezing hydrogel with high strength and strong adhesion, further expanding the potential applications of hydrogel-based sensors and energy harvesting systems in low temperature environment.
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关键词
Conductive hydrogel,Hydrated lithium ion,Triboelectric nanogenerators,Biomechanical sensor,Energy harvesting device
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