Nitrooxylative Dearomatization Reaction of Β‐naphthols with Hypervalent Iodine Reagent
ASIAN JOURNAL OF ORGANIC CHEMISTRY(2024)
摘要
A catalyst‐free intermolecular dearomatization reaction of β‐naphthols with hypervalent‐iodine‐based nitrooxylating reagent is reported. Various nitrooxylated β‐naphthalenones bearing a quaternary carbon stereogenic center were obtained smoothly in good to excellent yields (up to 87 %) under mild conditions. This method features mild conditions, broad substrate scope and excellent chemoselectivity.
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关键词
dearomatization,hypervalent iodine reagent,β-naphthol,nitrooxylative
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