Cyclic (amino)(barrelene)carbene Ru-complexes: synthesis and reactivity in olefin metathesis

The synthesis of ruthenium-complexes with cyclic (amino)(barrelene)carbenes (namely CABCs) as ligands is reported. Isolated in moderate to good yields, these new complexes showed impressive thermal stability at 110 degrees C over several days. Good catalytic performances were demonstrated in various ring-closing metathesis (RCM), macrocyclic-RCM, ring-closing enyne metathesis (RCEYM), cross-metathesis (CM), and ring-opening cross metathesis (ROCM) reactions. The first cyclic (amino)(barrelene)carbene (CABC) Ru-complexes were synthesized. They demonstrated remarkable thermal stability at 110 degrees C and good performance in olefin metathesis.