Hydrophilic surface modification of polypropylene by AC-DBD and NS-DBD

Dielectric barrier discharge (DBD) is a method to modify material surfaces by creating low-temperature plasma at atmospheric pressure. However, in comparison to low-pressure discharge, atmospheric DBD has the drawback of uneven surface treatment due to the ease of forming filamentary channels. This limitation hinders the widespread application of DBD technology in material surface modification. In this study, the surface of polypropylene (PP) was treated using high frequency alternating current (AC) and nanosecond (NS) pulsed argon DBDs to improve surface hydrophilicity. The changes of the PP surface hydrophilicity and the treatment uniformity were characterized by water contact angle (WCA) measurement. The relationships between the DBD characteristics, the treatment effect and the treatment uniformity of the PP surface were investigated using electrical and optical diagnostic techniques. The PP material surfaces before and after plasma treatments were evaluated by the physical morphology and chemical composition measurements to examine the influence of DBD on the treatment effect and uniformity on the PP material surface. The findings show that the modification by AC-DBD reduces the WCA of PP material surface by 40°∼50° and exhibits a variance of 1.77, indicating an improvement in hydrophilicity to some extent. Furthermore, the modification by NS-DBD further decreases the WCA of PP material surface, reducing the variance to 1.14. Compared with AC-DBD, NS-DBD has a better uniformity, a higher concentration of active particles in plasma, a greater surface roughness of PP material after treatment, a better hydrophilicity and a more uniform effect with less energy consumption. The results are meaningful to improve the application of DBD in material surface modification and optimize the power source election and operation parameters.