Quantitative Measurements of Catalytic Activity of Single-Atom and Nanoparticle Palladium Catalysts for Sensitive Detection of Methane Using Cantilever-Based Temperature-Programmed Reduction Technique
2024 IEEE 37TH INTERNATIONAL CONFERENCE ON MICRO ELECTRO MECHANICAL SYSTEMS, MEMS(2024)
摘要
In this work, the catalytic activity of isolated single atoms (SAs) was quantitatively measured using an integrated resonant microcantilever, which can measure sub-picogram-level mass-changes of Pd-SAs during the reduction process under an H 2 -containing atmosphere (i.e., cantilever-based H 2 -TPR technique). The ultra-sensitive cantilever-TPR measurements indicate that Pd-SAs exhibit higher catalytic activity than Pd nanoparticles with an average diameter of 3nm. The higher catalytic activity of Pd-SAs can be verified through gas sensing experiments because Pd-SAs show satisfactory responses to ppm-level methane. In contrast, the response of Pd-NPs to 100 ppm methane is negligible.
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关键词
Resonant microcantilever,Nanomaterial,Single atoms,Hydrogen temperature-programmed reduction technique
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