Simultaneous Compression of NaCl, Au, and Ruby: Toward Mutually Consistent Pressure Scales

HIGH PRESSURE RESEARCH(2024)

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摘要
We evaluate pressure consistency of equations of state (EOS) for NaCl and Au at 300 K. The simultaneous measurements of unit-cell volumes (V) with ruby R1 line shifts (Delta lambda) in a helium (He) loaded diamond cell effectively remove potential systematic errors. Compression and decompression data were automatically collected at 1 sec interval, yielding a dense dataset with >8,000 (V, Delta lambda) pairs each for NaCl and Au. Solidification of He has noticeable effects on both V and Delta lambda (hence P). Only data up to similar to 14 GPa, or 6000 (V, P) pairs, can be considered hydrostatic within the resolution. The P-V data are fitted to the Rydberg-Vinet and the 3(rd) order Birch-Murnaghan EOS. Predicted pressures of these EOSs agree with those given by the Ruby2020 ruby scale to within +/- 0.05 GPa. Overall, pressures predicted by the Rydberg-Vinet EOS are in better agreement with the average of commonly used NaCl and Au pressure scales.
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关键词
High pressure X-ray diffraction,hydrostaticity,Rydberg-Vinet equation of state,Birch-Murnaghan equation of state,ruby pressure scales
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