A photocatalyst with an enhanced Schottky effect and an efficient electron-transfer channel fabricated by assembling Ni-WC heterojunction nanoparticles on g-C₃N₄ for highly efficient removal of chlorophenols

Fabricating photocatalysts with optimized charge kinetics to improve carrier transfer and separation is critical for the removal of highly-toxic chlorophenol pollutants. Herein, a Mott-Schottky catalyst was fabricated by assembling nickel-tungsten carbide nanoparticles on two-dimensional g-C3N4 (Ni-WC/CN) for the photocatalytic removal of 4-chlorophenol (4-CP). The abundant interfacial contact and suitable Fermi level alignments between g-C3N4 and Ni-WC induced an enhanced Schottky effect and an efficient photogenerated electron transfer route from g-C3N4 to Ni-WC. The electron-rich Ni-WC surface could effectively activate oxygen/water molecules to generate active radicals. Consequently, Ni-WC/CN boosts the photodegradation and mineralization of 4-CP with 100% removal rate, 100% mineralization efficiency and fast rate constant (k(ap), 3.0 x 10(-2) min(-1)) in 2.5 h under 100 W white light. The k(ap) and mineralization efficiency of Ni-WC/CN are 30-fold and 49-fold higher than those of g-C3N4. The robust Ni-WC/CN also exhibited excellent substrate universality in CP removal and ensured biological safety of the treated water. This work provides evidential proof of the rational design of efficient Schottky photocatalysts via the regulation of electron transfer on heterostructure interfaces in practical environmental applications.