Thermodynamics of Mixtures Containing a Strongly Polar Compound. 9. Liquid-Liquid Equilibria for ϵ-CAPROLACTAM + Selected Alkanes
arxiv(2024)
摘要
The coexistence curves of the liquid-liquid equilibria (LLE) for systems of
-caprolactam with heptane, octane, nonane, decane or 2,2,4-trimethylpentane
have been determined by the method of the critical opalescence using a laser
scattering technique. All the curves show an upper critical solution
temperature (UCST), have a rather horizontal top and their symmetry depends on
the size of the alkane. The UCST increases almost linearly with the chain
length of the n-alkane. For the octane mixture, the UCST is lower than for the
solution including 2,2,4-trimethylpentane.
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