Liquid-crystalline circularly polarised fluorescent emitters with a high luminescence dissymmetry factor
CHEMICAL COMMUNICATIONS(2024)
摘要
Chiral liquid-crystalline emitters based on 9,9-dimethyl-10-(4-(phenylsulfonyl)phenyl)-9,10-dihydroacridine and a functionalised binaphthol show smectic liquid crystal phases and circularly polarised blue fluorescence with a high luminescence dissymmetry factor |glum| of 0.13. Solution-processable organic light-emitting diodes (OLEDs) based on the enantiomers were explored. Chiral liquid-crystalline emitters based on 9,9-dimethyl-10-(4-(phenylsulfonyl)phenyl)-9,10-dihydroacridine and binaphthol show smectic mesophases and circularly polarised blue fluorescence with a high luminescence dissymmetry factor |glum| of 0.13.
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