C20H4(C4F8)3: A Fluorine‐Containing Annulated Corannulene That is a Better Electron Acceptor Than C60

Mal sechs, mal sieben: Die Reaktion von Corannulen mit 35 Äquivalenten 1,4-C4F8I2 führt recht selektiv zu zwei Hauptprodukten, in denen sechs H-Atome durch drei C4F8-Einheiten substituiert sind, die sechs- und siebengliedrige Ringe bilden. Tieftemperatur-Photoelektronenspektroskopie zufolge hat das Hauptisomer (siehe Struktur) eine höhere Elektronenaffinität als C60 (2.74±0.02 bzw. 2.689±0.008 eV). As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.