Biological assays, electrochemical behavior, and theoretical DFT calculations of Ru(II) complexes of chiral phosphinite based based on β-amino alcohols: Transfer hyrogenation of ketones using a HCOOH/Et3N mixture

Khadichakhan Rafikova,Nermin Meriç,Nil Ertekin Binbay,Veysi Okumuş, M. Şerif Sever,Yelizaveta Belyankova, Saniya Tursynbek,Anuar Dauletbakov,Bayazit Sarah,Darya Zolotareva, Kamshyger Yerassyl, Abdurahman Dündar,Remziye Güzel,Murat Aydemir

Journal of Molecular Structure（2024）

引用 0|浏览4

暂无评分

摘要

•The ruthenium complexes were studied theoretically using DFT/CAM-B3LYP level.•Hardness and HOMO-LUMO gap of the complexes including benzene fragment were lower.•The complexes had antioxidant, antimicrobial and DNA binding activities.•The ruthenium-based variants have different redox potentials.•Complex 8 was used in ATH in the presence of HCOOH-Et3N mixture as reducing agent.

查看译文

关键词

Asymmetric transfer hydrogenation (ATH),Β-amino alcohols,DFT and CAM-B3LYP,Electrochemical properties,CA and OCPA,Biological assay

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要