Photo-thermo-electric Hydrogel with Interlocking Photothermal Layer and Hydrogel for Enhancement of Thermopower Generation

Photothermal devices and thermoelectric cells hold great promise for energy generation but integration of the two remains a considerable challenge in real-life power supply for sensors. Here, a novel photo-thermo-electric hydrogel (PTEH-Interlocking) was constructed by the synthesis of a photothermal layer on a thermoelectric hydrogel with the redox pair Fe(CN)63-/Fe(CN)64-. The smart design of using the oxidation of pyrogallic acid by Fe(CN)63- to construct the photothermal layer for photo-to-heat conversion protected the redox couple of the thermogalvanic ion pair from ultraviolet damage, as well as triggered the formation of an interlocking structure at the interface of the photothermal layer and the thermoelectric hydrogel. The as-prepared PTEH-Interlocking has shown a high Seebeck coefficient and rapid heat transfer, boosting the photo-thermo-electric conversion. As a demonstration of a practical application, the PTEH-Interlocking cells are successfully used as the energy supply for a mechanical sensor.image Photo-thermo-electric hydrogel with an interlocking structure at the interface (PTEH-Interlocking) was developed by assembling polyphenol photothermal film on the surface of redox thermoelectric hydrogels. This smart design improved the stability through protecting the internal redox couple from UV damage, as well as improve the photo-thermal-electric conversion efficiency, which realizes the use of solar energy to power miniature sensors.image