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Syntheses and Characterizations of Naphtho-rhenafuran Complexes with S0 and T0 States

Liyan Zhan, Yarong Wang, Caobo Sun,Junping Tang,Yue Zhao,Yan Zhou,Yang Li,Limei Yu,Wei Bai

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY（2024）

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Abstract
Reactions of o-alkyl naphthol compounds with ReCl3(PMePh2)(3) produced naphtho-rhenafuran complexes, which adapted different ground states (singlet S(0 )and triplet T-0). These polycyclic structures have been characterized experimentally and theoretically. Their electronic behaviors have been studied by UV-Vis absorption and DFT calculations.
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alkynyl naphthalenol,ground state,metallacycle,rhenium,UV-Vis
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