Influence of Preparation Effects on 10 Wt. %cuo/mno X Catalytic Activity in the Preferential Oxidation of CO (CO-PROX)
Research on Chemical Intermediates(2024)
摘要
This study focused on the preparation of 10wt% CuO/MnO x catalysts using three different MnO x supports synthesized via hydrothermal, mechanochemical, and solution combustion methods. The catalysts were evaluated for preferential oxidation of CO for hydrogen purification within a temperature range of 40–250 °C at a gas hourly space velocity of 30000 (ml/(h.g cat )). Characterization of the synthesized catalysts was carried out using X-ray diffraction, Brunauer–Emmett–Teller, H 2 temperature-programmed reduction (H 2 -TPR), and scanning electron microscopy analyses. Results showed that the employed method for the preparation of the catalyst support significantly affects the reduction temperature and the oxidation state of the final catalysts. The 10 wt% Cu/Mn-CMB catalyst exhibited better reducibility, higher CO conversion at 100 °C (94%), and appropriate catalytic stability in the presence of H 2 O and CO 2 compared to the other samples.
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关键词
Hydrogen,Hydrothermal,Mechano-chemical,Solution combustion,CO-PROX
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