Cyclopentadienyl Capped Thorium(iv) Porphyrinoid Complex.

Daniel N. Mangel,James T. Brewster,Gabriel J. Juarez,Vincent M. Lynch,Jonathan L. Sessler

Chemical communications（2024）

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摘要

The reaction between Th(IV) dipyriamethyrin dichloride and sodium cyclopentadienyl (Cp) results in the formation of a cyclopentadienyl capped thorium dipyriamethyrin complex, which to our knowledge represents the first expanded porphyrin f-element Cp complex.

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