Moisture Diffusion Affected by the Knudsen Effect in Temporal Changing Pore Networks

Almost all building materials in civil engineering have an open porosity and interact with or are affected by the environmental conditions. Structures might suffer from effects such as moisture adsorption, carbonation, corrosion, penetration of salt ions and chemical substances, etc. In the hygroscopic range, these processes are mostly driven by diffusion. Due to the confinement of small pores (less than1 µm), the Knudsen effect reduces the molecular diffusion. This reduction can become more significant in case of temporal changing pore systems because of physisorption of water vapor, carbonation, or chemisorption.