Leaching Behavior of Rare Earth Elements from Waste NdFeB Magnets Utilizing Deep Eutectic Solvents

The leaching behavior of a rare earth element, neodymium, from waste NdFeB magnets using deep eutectic solvents (DESs) was investigated.Eight different DESs were prepared for leaching tests.The basic tests were conducted on Nd and Fe compounds, Nd 2 O 3 , Fe, and Fe 2 O 3 .Using GUC-LAC, ChCl-LAC, and EG-MA, Nd 2 O 3 was leached by 64-100%.With the three DESs, Fe exhibited a leaching efficiency of over 94% in all DESs, while that of Fe 2 O 3 remained low at <7%.Based on the results, leaching tests were conducted on NdFeB magnets with and without oxidative roasting.The leaching efficiencies of Nd and Fe significantly decreased after the roasting, at 27% and 4.7%, respectively.This was attributed to the formation of NdFeO 3 during the roasting.Therefore, to selectively recover Nd from NdFeB magnets, the application of the appropriate pre-treatment method is necessary, prioritizing the separation of individual oxides to Nd 2 O 3 and Fe 2 O 3 .