Extraction and Characterization of Two Residual Lignins from Eucalyptus Wood

Lignin, the second most abundant biopolymer on the planet, has properties that can be widely explored, moving from waste to products with high added value. Therefore, this work aimed to extract and characterize Klason and Kraft lignins from sawdust and black liquor, considered industrial waste. The raw material used was Eucalyptus grandis chips. To obtain Klason lignin according to TAPPI 222 om-02 (2002), part of the chips were transformed into sawdust. To obtain Kraft lignin, another part of the chips passed through a digester to obtain black liquor, which was subsequently subjected to acid precipitation. The characterization of lignins was performed by granulometry analysis, scanning electron microscopy with elemental chemical analysis (EDS), transmission electron microscopy, medium infrared spectroscopy, thermogravimetric analysis and differential calorimetry. Microscopy analyzes showed irregular structures of various shapes, including spherical structures, most evident and frequent in Kraft lignin. The elementary chemical analysis showed that the lignin washing process was satisfactory, due to the small percentage of sulfur detected in the samples. The results of the granulometry confirmed that the lignins had micrometric dimensions. The medium infrared spectra showed the characteristic peaks of the chemical composition of lignin. The thermal analysis showed three ranges of degradation, attributed to the drying of the samples, degradation of the hemicelluloses and the lignin itself. All results confirmed the obtaining of Klason and Kraft lignins. Therefore, the techniques were satisfactory in transforming waste into lignin with the potential for a variety of commercial applications, mainly in the chemical and pharmaceutical industries.