Potassium-39-derived 36ar Production During Fission-Neutron Irradiation and Its Effect on 40ar/39ar Ages

Various interference reactions producing unwanted Ar isotopes from K, Ca, Cl and Ar require correction to satisfy the 40Ar/39Ar age equation. Using GEANT4, we design and build a model Cadmium Lined In Core Irradiation Tube (CLICIT) irradiation facility, as used in the Oregon State TRIGA Reactor (OSTR). We illustrate the complexity of the irradiation of geologic samples within this framework and determine an overlooked production channel of 36Ar. The production of 36Ar is fed from the 39K(n,& alpha;)36Cl nuclear channel, 36Cl subsequently decays to 36Ar (39K(n,& alpha;,& beta;) 36Ar). Simulations in this work using a 235U fission neutron energy spectrum and modelled CLICIT facility, determine a production ratio for this reaction (36Cl/39Ar)K = 0.40 & PLUSMN; 0.01 (1 & sigma;); greater than an order of magnitude larger than any other K interference. The magnitude of the resulting age bias for an unknown sample will be a function of the integrated neutron flux, the length of irradiation (fluence), the time elapsed since irradiation, and the age relationship between the unknown and neutron fluence monitor. We show using the raw data of (Niespolo et al., 2017) that the age of Alder Creek sanidine can be modified to be ca. 0.1% older (1 & sigma;), at the 2 & sigma; level of current analytical precision for the Alder Creek age for this study. The 39K(n,& alpha;,& beta;)36Ar inference should be incorporated into routine data analysis and may be especially important in the intercalibration of the 40Ar/39Ar system with other chronometers (e.g., 206Pb/238U).