Experimental evidence for CH⋯π interaction-mediated stabilization of the square form in phenylglycine-incorporated ascidiacyclamide

Akiko Asano,Katsuhiko Minoura,Takeshi Yamada,Mitsunobu Doi

RSC Advances（2023）

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摘要

The thermodynamic parameters through NMR-based quantitation provided evidence for the CH⋯π interaction in phenyl group-incorporated ascidiacyclamide. Stabilization of the square form by CH⋯π interaction resulted in increased cytotoxicity.

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关键词

stabilization,interaction-mediated,phenylglycine-incorporated

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