Organosilicon Derivatives Based on 2-Aminothiazolium Cations

N. O. Yarosh,I. A. Dorofeev,L. V. Zhilitskaya

Russian journal of organic chemistry（2023）

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摘要

The reactions of 2-aminothiazole and 2-aminobenzothiazole with iodomethyl silanes in the absence of a base gave previously unknown organosilicon salts and ionic liquids derived from 2-aminothiazole and 2-aminobenzothiazole. The structure of the synthesized compounds was proved by NMR and UV spectroscopy.

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关键词

2-amino-1,3-thiazole,2-amino-1,3-benzothiazole,1-(iodomethyl)trimethylsilane,1-(iodomethyl)dimethylphenylsilane,1-(iodomethyl)dimethylethynylsilane,1-(iodomethyl)(dimethyl)[2-(trimethylsilyl)ethynyl]silane,1-(iodomethyl)(dimethyl)(2-phenylethynyl)silane,silylalkylation,iodides,triiodides

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