Mechanistic Insights into the Electrochemical Reduction of CO2 to CO on Ni(salphen) Complexes

Sara Realista,Paulo J. Costa,Luisa B. Maia,Maria Jose Calhorda,Paulo N. Martinho

INORGANIC CHEMISTRY FRONTIERS（2023）

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摘要

Ni(salphen) reduces CO 2 to CO via a double reduction/protonation mechanism, and the active species binds to CO, only releasing stoichiometric amounts of CO upon exposure to air. This has been confirmed in both experimental and computational studies.

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关键词

CO2 Reduction,CO2 Capture

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