Nickel-Catalyzed Isomerization of Homoallylic Alcohols

Dustin D. Youmans,Hai N. Tran,Levi M. Stanley

Organic letters（2023）

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摘要

Nickel-catalyzed isomerizations of homoallylic alcohols and a bishomoallylic alcohol are presented. These isomerization reactions occur in the presence of a simple nickel catalyst that does not require addition of an exogenous ligand. The corresponding ketone products are generated in ≤98% yield.

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