Unpredicted Coordination of Hydrogen Chloride in Organoruthenium(ii) Pyrazolone Complex: Synthesis, Spectral and Structural Characterization
Inorganic chemistry communications/Inorganic chemistry communications (Online)(2023)
摘要
Synthesis of novel Ru(II) carbonyl and Ru(II) hydride complexes is reported from the reaction of 4-(2-hydroxybenzyl)-3-methyl-5-oxo-2,5-dihydro-pyrazole-1-carbothioic acid ethyl amide with RuHCl(CO)(PPh3)3. Structural evaluations were done by FT-IR, UV-Vis, 1H NMR and mass spectrometry. The true nature of the Ru(II) complexes was further confirmed by single crystal X-ray diffraction studies and further validated by DFT studies. The electrochemistry of the synthesized complexes was studied using cyclic voltammetry.
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关键词
Ru(II) hydrogen chloride complex,Unusual coordination of hydrogen chloride,X-ray crystallography,Pyrazolone ligand,NMR spectroscopy,Cyclic voltammetry
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