Fabrication of Phosphoric-Crosslinked Chitosan@g-C3n4 Gel Beads for Uranium(vi) Separation from Aqueous Solution.

In this work, a novel g-C3N4 filled, phosphoric-crosslinked chitosan gel bead (P-CS@CN) was successfully pre-pared to adsorb U(VI) from water. The separation performance of chitosan was improved by introducing more functional groups. At pH 5 and 298 K, the adsorption efficiency and adsorption capacity could reach 98.0 % and 416.7 mg g 1, respectively. After adsorption, the morphological structure of P-CS@CN did not change and adsorption efficiency remained above 90 % after 5 cycles. P-CS@CN exhibited an excellent applicability in water environment based on dynamic adsorption experiments. Thermodynamic analyses demonstrated the value of & UDelta;G, manifesting the spontaneity of U(VI) adsorption process on P-CS@CN. The positive values of & UDelta;H and & UDelta;S showed that the U(VI) removal behavior of P-CS@CN was an endothermic reaction, indicating that the increase of temperature was great benefit to the removal. The adsorption mechanism of P-CS@CN gel bead could be summarized as the complexation reaction with the surface functional groups. This study not only developed an efficient adsorbent for the treatment of radioactive pollutants, but also provided a simple and feasible strategy for the modification of chitosan-based adsorption materials.