Application of a Hybrid GEM-CMB Model for Source Apportionment of PAHs in Soil of Complex Industrial Zone.

Accurate source apportionment is essential for preventing the contamination of pervasive industrial zones. However, a limitation of traditional receptor models is their negligence of transmission loss, which consequently reduces their accuracy. Herein, chemical mass balance (CMB) and generic environmental model (GEM) was fused into a new method, which was employed to determine the traceability of polycyclic aromatic hydrocarbons (PAHs) in a complex zone containing three coking plants, two steel plants, and one energy plant. Five categories of fingerprints comprising various compounds were established for the six plant sources where seven PAHs with low-high rings were screened as the best. Considering volatilization, dry deposition, and advective and dispersive transport, the GEM model generated 232 "compartments" in multimedia to capture subtle variations of PAHs during transmission. More than 90 % of the transmission of the seven PAHs varied between 0.4 % and 6.0 %. Over pure CMB model, acceptable results and best-fit results improved by 1.6-44.4 % and 0.3-80.8 % in the GEM-CMB model. Additionally, the coking, steel, and energy industries accounted for 36.4-56.1 %, 25.6-41.7 %, and 18.3-23.6 % of PAHs sources at four receptor points, respectively. Furthermore, quantifying contaminant loss rendered the traceability results more realistic, judged by distances and discharge capacities. Accordingly, these outcomes can help in precisely determining soil contamination.