Deposition and Spread of Aqueous Pesticide Droplets on Hydrophobic/Superhydrophobic Surfaces by Fast Aggregation of Surfactants.

Deposition and spread of aqueous droplets on hydrophobic/superhydrophobic surfaces are of great significance in many practical applications, such as spraying, coating, and printing, and particularly in improving pesticide utilization efficiency because the intrinsic hydrophobicity/superhydrophobicity of most plant leaves results in serious loss of water-based pesticides during spraying. It has been found that proper surfactants can promote the droplet spread on such surfaces. However, most reports involved the effects of surfactants on the spread of the gently released droplets over hydrophobic or highly hydrophobic substrates, while the situation on superhydrophobic substrates has rarely been explored. Moreover, high-speed impact makes it extremely difficult to deposit and spread the aqueous droplets on superhydrophobic surfaces; thus, the deposition and spread have just been achieved by surfactants in recent years. Here, we give an overview concerning the influence factors on the deposition and spreading performance of gently released and high-speed impacted droplets on hydrophobic/superhydrophobic substrates and emphasize the effects of fast aggregation of surfactants at the interface and in solution. We also outline perspectives on the future development of surfactant-assisted deposition and spreading after high-speed impact.