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Iridium(i) Complexes with Bidentate NHC Ligands As Catalysts for Dehydrogenative Directed C–H Silylation

Romane Manguin,Maria Galiana-Cameo,Tanakorn Kittikool,Cecile Barthes,Jompol Thongpaen, Etienne Bancal,Sonia Mallet-Ladeira,Sirilata Yotphan,Ricardo Castarlenas,Marc Mauduit,Jean-Baptiste Sortais,Olivier Basle

Chemical communications（2023）

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Abstract
A series of (NHC)(cod)Ir(I) complexes bearing NHC-carboxylate ligands were efficiently synthesized and fully characterized. Their solid-state structures confirmed the bidentate coordination mode of these LX-type NHC ligands. These unprecedented iridium(I) complexes demonstrated efficient catalytic activities in dehydrogenative directed C-H silylation of arenes, and allowed for excellent ortho-selectivity control with aromatic silylating agents.
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