Inverse 'Intra-Lattice' Charge Transfer in Nickel-Molybdenum Dual Electrocatalysts Regulated by Under-Coordinating the Molybdenum Center.

Sahanaz Parvin,Neha Bothra,Supriti Dutta,Mamoni Maji, Maglu Mura,Ashwani Kumar,Dhirendra K. Chaudhary,Parasmani Rajput,Manvendra Kumar,Swapan K. Pati,Sayan Bhattacharyya

Chemical science（2023）

Cited 0|Views17

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Abstract

An unorthodox intra-lattice ‘inverse’ charge transfer occurs from the undercoordinated Mo-center to neighbouring Ni-centers in the Ni73Mo alloy (−) and NiMo-hydroxide (+). The self-supported couple splits alkaline water at 1.48 V at 10 mA cm−2.

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