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NiFeP Anchored on Rgo As a Multifunctional Interlayer to Promote the Redox Kinetics for Li–S Batteries Via Regulating D-Bands of Ni-Based Phosphides

ACS SUSTAINABLE CHEMISTRY & ENGINEERING(2023)

Xiangtan Univ | Natl Univ Def Technol

Cited 16|Views14
Abstract
Sluggish kinetics of polysulfide redox reaction give rise to poor electrochemical properties for lithium-sulfur (Li-S) batteries. Electrocatalysts are introduced to decrease activation energy and effectively accelerate the dynamics of polysulfide conversion. In this study, we propose a rational strategy of tuning the d-band of catalysts via delivering Fe into Ni2P in situ grown on rGO to construct NiFeP/rGO composites. Based on the first-principles density functional theory calculation, the metallic conduction of Ni2P could be improved by Fe incorporation, facilitating a charge transfer electrocatalytic interface for redox reaction of LiPSs. Moreover, the d-band center of NiFeP also elevates to the Fermi level after incorporation with Fe, which could weaken the S-S bonds of polysulfides due to its redistributed electron population and reduce the activation barrier. Therefore, NiFeP/rGO composites as the functional interlayer for Li-S batteries can not only promote the interaction between polysulfides and NiFeP but also accelerate the conversion of polysulfides. They exhibit a high initial discharge capacity of 1261 mAh g-1 at 0.2 C and an outstanding rate reversible capacity of 671 mAh g-1 even at a high rate of 2 C. The high-efficiency NiFeP/rGO electrocatalyst with a rational structure for Li-S batteries testifies to the availability of the d-band regulating strategy with the low-activation-energy barrier and promotes an in-depth understanding of LiPSs redox reaction at the molecular or atom level.
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Li-S batteries,NiFeP anchored on rGO,multifunctional interlayer,regulating d-band strategy,redox kinetics
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要点】:本研究提出了一种通过调节镍基磷化物d带的方法,以促进锂硫电池中多硫化物氧化还原反应的动力学性能,创新点在于通过Fe原位掺杂Ni2P并负载于还原氧化石墨烯(rGO)上制备NiFeP/rGO复合物,实现高效电催化作用。

方法】:通过原位生长方法将Fe掺杂到Ni2P中,并与rGO结合,利用第一性原理密度泛函理论计算优化催化剂的电子结构。

实验】:使用NiFeP/rGO复合材料作为锂硫电池的功能性中间层,实验结果显示该复合材料在0.2 C下具有1261 mAh g^-1的高初始放电容量,并在2 C的高速率下仍保持671 mAh g^-1的可逆容量。数据集未在文中明确提及。