Nanofibrous Janus Membrane with Improved Self-Cleaning Property for Efficient Oil-in-water and Water-in-oil Emulsions Separation

Developing a membrane integrating high separation efficiency and good anti-fouling ability for both oil-in-water and water-in-oil emulsions is meaningful due to the complexity and diversity of actual oily wastewater. Herein, a facile strategy was designed to generate a nanofibrous Janus membrane to achieve multifunctional and self-cleaning properties. Hydrophilic beta-FeOOH was anchored on poly(vinylidene fluoride-co-hexa-fluoropropylene) (PVDF-HEP) fibers to achieve hydrophilicity and self-cleaning performance of PVDF-HEP/beta-FeOOH layer by in situ mineralization technology. The Janus membrane was then obtained by incorporating PVDF-HEP fibers layer onto the hydrophilic layer through electrospinning technology. PVDF-HEP/beta-FeOOH layer owns super-hydrophilicity (WCA = 0 degrees) and underwater superoleophobicity (OCA = 159 degrees), which can separate different surfactant-stabilized oil-in-water emulsions with separation efficiency of above 99.8 % when this layer is facing up. Conversely, the PVDF-HEP layer exhibits superhydrophobicity (WCA = 149 degrees), which can separate different surfactant-stabilized water-in-oil emulsions with separation efficiency of above 99 % when this layer is facing up. More importantly, a satisfying water flux recovery rate of 98.2 % is acquired due to the synergistic effect between beta-FeOOH photocatalysis and asymmetric wettability of the membrane, endowing the membrane with effective self-cleaning capability and satisfactory stability. This study provides a new strategy for designing multifunc-tional membrane toward actual complex oily wastewater treatment.