Synthesis of a transesterification vitrimer activated by fluorine from an α,α-difluoro carboxylic acid and a diepoxy

Florian Cuminet,Sylvain Caillol,Éric Dantras,Éric Leclerc,Sébastien Lemouzy,Cédric Totée,Olivier Guille,Vincent Ladmiral

European Polymer Journal（2023）

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摘要

•An α,α-difluorodicarboxylic acid was synthesized.•The reaction of the diacid with a diepoxy led to a 3D network.•The polyester material obtained is a catalyst-free vitrimer.

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关键词

Vitrimer,Catalyst-free,Polyester,Crosslinking,Difunctional,Fluorine

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