The earliest Neoproterozoic Nb-enriched mafic magmatism indicates subduction tectonics in the southwestern Yangtze Block, South China

To better reveal the early Neoproterozoic tectonic process of South China with respect to the assembly of the Rodinia supercontinent, an integrated dataset of geochronology, whole-rock geochemistry, and Sr-Nd-Hf isotopic compositions for diabases that intruded the Kunyang Group in the southwestern Yangtze Block is herein presented. Zircon U-Pb dating gives four weighted mean 206Pb/238U ages of 946 ± 4 Ma, 948 ± 6 Ma, 939 ± 4 Ma, and 918 ± 7 Ma, suggesting mafic magmatism in the earliest Neoproterozoic. The diabases possess Nb = 12.3–30.5 ppm, Nb/U = 19.99–37.06, Nb/La = 0.78–1.05, (Nb/Th)PM = 0.44–0.80, and (Nb/La)PM = 0.75–1.02, geochemically resembling those of typical Nb-enriched basalts. They are tholeiitic in composition with low SiO2 (49.49–51.95 wt%), high TiO2 (2.03–4.65 wt%), MgO (2.50–6.14 wt%), and Fe2O3T (15.38–18.84 wt%) contents. They are enriched in light rare earth elements (LREEs) with weak negative Eu anomalies (Eu/Eu* = 0.75–0.96) and show E-MORB-like characteristics with slight to moderate Nb-Ta depletion. The samples show zircon εHf(t) values ranging from + 5.8 to + 10.3 and whole-rock εNd(t) values from + 0.5 to + 0.9. These elemental and isotopic characteristics suggest that the 0.95–0.92 Ga diabases may have derived from an E-MORB-like magma source with the injection of metasomatized slab melts. Integrating previous studies with our results, we propose that the southwestern Yangtze Block evolved from an intracontinental rift to a passive continental margin in the late Mesoproterozoic, followed by the development of an earliest Neoproterozoic continental arc-back-arc basin system analogous to the Northern Okinawa Trough. The distinct tectonic processes between the southern and northern parts of the Yangtze Block at ca. 1.0–0.9 Ga favour the hypothesis that the final cratonization of the present-day Yangtze Block occurred slightly later than ∼ 0.9 Ga in response to the Rodinia supercontinent assembly.