Higher corrections of the Ilkovich equation

S. Jon Chapman,Charles W. Monroe,Shiv Krishna Madi Reddy,Alexander Van-Brunt,Ralph E. White

Journal of Electroanalytical Chemistry（2022）

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摘要

•Ilkovic polarography equation derived and augmented.•Asymptotic analysis leads systematically to higher-order terms.•Newman’s 1st-order correction verified; 2nd-order correction computed for the first time.•Asymptotic methods compared to accurate numerical computation.

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关键词

Polarography,Dropping mercury electrode,Diffusion,Limiting current,Transport phenomena

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