The Original and Impactful Exploitation of Chemical Energy in Heat Pumps

In light of reducing carbon emissions and the tension on non-renewable energy sources, heat pumps are being investigated as an alternative to fossil-fuel-dependent energy converters in heat demanding applications. On the basis of the impactful results the authors obtained in previous research around the potential of using reactive fluids–instead of inert ones–as novel working fluids in power cycles, the study has been extended to heat pump systems. The thermodynamic analysis of heat pumps operating with reactive gases as working fluids is thus the objective of the present work. More specifically, the analysis is based on the use of instantaneously equilibrated fictive gaseous reactions, with the aim to thoroughly assess the impact of different stoichiometries and thermochemical characteristics of chemical reactions. This studied heat pump is based on the reverse Brayton cycle. Furthermore, the behavior of the fluid in each unit operation of the cycle is investigated and all the results are compared to those of a heat pump utilizing comparable inert fluids; that is to preliminarily quantify the potential gains in performance. For the considered spectrum of reactive fluids, operating conditions, and reaction stoichiometries, the corresponding results show a range of potential reactive fluids that can be utilized in heat pumps and reveal an increase of more than 200% in the system's coefficient of performance compared to inert-fluid heat pumps.