Boronic Ester Functionalised 1,8-Diboryl-naphthalene Scaffolds: Fluoride Versus Oxide Chelation.

Anna C. Booth,Petra Vasko,M. Angeles Fuentes,Bart Cornelissen,Stephen Faulkner,Simon Aldridge

Dalton transactions（2022）

Cited 0|Views13

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Abstract

1,8-C10H6(BCat)(BMes2) takes up F− to give a kinetic product featuring a bridging B–F–B unit. An alternative structural motif featuring a terminal B–F bond and a B–O–B bridge using one of the catechol oxygens is shown to be more favourable thermodynamically.

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