Photochemistry of pyruvic acid is governed by photo-induced intermolecular electron transfer through hydrogen bonds

Jennifer S. Lewis,Adam P. Gaunt,Arnaud Comment

Chemical Science（2022）

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摘要

When supercooled pyruvic acid is photo-irradiated, a radical detectable by ESR forms following the transfer of an electron from a molecule in its keto form to a molecule in its hydrated form. The latter subsequently degrades to CO2 and acetic acid.

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关键词

pyruvic acid,intermolecular electron transfer,hydrogen bonds,photo-induced

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