Molecular engineering of ruthenium-based photosensitizers with superior photovoltaic performance in DSSCs: novel N-alkyl 2-phenylindole-based ancillary ligands

In this work, we report the design and successful synthesis of two new heteroleptic polypyridyl Ru(II) complexes (SD-5 and SD-6), by incorporating hetero-aromatic electron-donating N-alkyl-2-phenylindole moieties into the ancillary ligand. These novel ruthenium complexes were used as photosensitizers for dye-sensitized solar cells. The primary objective was to investigate the electron-donating effect of the indole segments on the photo-related properties and the influence of the length of terminal alkyl chains tethered to N-indole on the charge recombination resistance. The chemical structures of both targeted compounds were confirmed via FT-IR, H-1-NMR and mass spectrometry. Under the same device fabrication conditions, the photovoltaic performance of SD-6 outperformed that of SD-5 and N719 with an overall efficiency of 8.14% (J(SC) = 19.21 mA cm(-2), V-OC = 0.675 V and FF = 62.7%), compared to 7.74% of N719 and 4.99% of SD-5. The enhanced photovoltaic power of SD-6 can be attributed to the presence of long alkyl antennas (-C18H37) in SD-6; it reduced the intermolecular aggregation of dyes and suppressed charge recombination, thus resulting in enhanced J(SC) and V-OC values, respectively, compared to its analog SD-5. Furthermore, the presence of indole moieties with long alkyl chains in the ancillary ligand enhanced the photovoltaic performance compared to N719 with bi-anchoring ligands. The photovoltaic and EIS measurements were consistent with the equilibrium molecular geometry calculated using density functional theory (DFT). The structure-property relationships have been discussed in detail.