Long-range transport of La Soufriere volcanic plume to the western North Pacific: Influence on atmospheric mercury and aerosol properties

Volcanic eruptions are important natural sources of gases and aerosols to the environment. However, their impact on the global cycle of trace elements, including mercury (Hg), remains poorly understood. On 9 April 2021, La Soufriere volcano (13.33 degrees N, 61.18 degrees W) erupted in the Caribbean Sea. Ozone Monitoring Instrument (OMI) measurements of sulfur dioxide (SO2) tracked the transport of volcanic SO2 in the troposphere over long distances from the source, including to the western North Pacific similar to 10 day after eruption. A spike in gaseous and particle-bound mercury concentrations along with a peak in aerosol back-scattering coefficient at Lulin Atmospheric Background Station (LABS, 23.47 degrees N, 120.87 degrees E; 2862 m AMSL) coincided with the volcanic plume transport on 19 April. The slope of gaseous elemental mercury vs. carbon monoxide concentrations during the event was 0.027, which is distinctly higher than for Southeast Asia biomass burning (slope = 0.005) and East Asia outflow (0.011) pollution sources. Arrival of the plume high above Taiwan was confirmed by significant changes in signature aerosol properties. Thus, with critical observational evidence, our study reported for the first time enhanced mercury levels similar to 18000 km downwind from a volcano source, providing an important check on volcanic Hg emission strength.