Development of zeolites for zeoforming reaction of naphtha

Malaysian Journal of Catalysis(2021)

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摘要
High octane naphtha production is the primary purpose of the zeoforming process that is genuinely needed in our modern life. Sulfur-containing compounds in gasoline are causing environmental pollution and catalysts deactivation. The metal function supplied by non-noble promoters such as Fe, Mn, Ni, Co, Cu, and Zn is deposited on the ZSM-5 type of zeolite. ZSM-5 zeolites were prepared by successive hydrothermal treatment following by impregnation of promoters on ZSM-5 type zeolite. The catalysts were characterized, utilizing XRD, N2 physisorption, FESEM, TEM, TPR-H2, and TPD-NH3. Bibliometric results show that feed conversion concerns are the primary focus in naphtha and zeolite topic studies. Particular attention has been paid to ZSM-5 and performance that may be crucial for improving the naphtha reforming reaction. The experimental results verified that different promoters' use has a profound effect on zeolites' physicochemical properties. It found that Fe interacts strongly with the ZSM5 zeolite producing growth in the metal function activity. The zeoforming results indicate that the highest research octane number (RON) belonged to the Fe promoter. A Fe promoter's existence increased the stability and selectivity for C7+ isomers and aromatics, thus reducing the formation of sulfur and lowvalue products like methane and gases.
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zeolites
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