A Removable Acyl Group Promoted the Intramolecular Dehydro-Diels–Alder Reaction of Styrene-Ynes: Highly Chemoselective Synthesis of Aryldihydronaphthalene Derivatives

The Journal of Organic Chemistry(2022)

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Abstract
A removable acyl group promoted the intramolecular didehydro-Diels–Alder reaction of styrene-ynes under mild reaction conditions is proposed. The reaction is free of metals and catalysts, is easy to perform, and exhibits good functional group tolerance, providing a highly chemoselective approach for obtaining the valuable aryldihydronaphthalene derivatives.
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Key words
synthesis,dehydro-diels–alder reaction,removable acyl group,styrene-ynes
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